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n2024-14_EN
ion. However, previous studies focused on the crystallization of one of the ( S Si )- and ( R Si )-diastereomers, with the ( S Si )-diastereomer crystallizing faster. A selective fractional crystallization [...] diastereomers with excellent stereochemical purity. During these studies, both diastereomers, ( S Si )- 3 und ( R Si )- 3 , were isolated in good yields and fully characterized. By employing single-crystal [...] Interactions as Key in Racemic Resolution: New Insights into the (SSi)- and (RSi)-Diastereomers of (1R,2S,5R)-Methyl(1-naphthyl)-phenylmenthoxysilane of Sommer J.-L. Kirchhoff, C. Strohmann, Z. anorg. allg. Chem …